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Publications 2011-2020

2020
253. “Rhodium-Catalyzed Cyclization of Terminal and Internal Allenols: An Atom-Economic and Highly Stereoselective Access Towards Tetrahydropyrans”

Johannes P. Schmidt, B. Breit, Angew. Chem. 2020, 132, 23691-23696. (link) Angew. Chem. Int. Ed. 2020, 59, 23485-23490. (link)
 
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252. “Amin Acid-Based Dithiocarbamates as Efficient Intermediates for Diversity-Oriented Synthesis of Thiazoles”

A. Z. Halimehjani, M. Khalesi, B. Breit, Eur. J. Org. Chem. 2020, 6081-6084. (link)
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251. “Synthesis of Thailandepsin B Pseudo-Natural Products: Access to New Highly Potent HDAC Inhibitors via Late-Stage Modification”

J. Brosowsky, M. Lutterbeck, A. Liebich, M. Keller, D. Herp, A. Vogelmann, M. Jung, B. Breit, Chem. Eur. J. 2020, 26, 16241-16245. (link)
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250. “Ligand-Mediated Regioselective Rhodium-Catalyzed Benzotriazole-Allene Coupling: Mechanistic Exploration and Quantum Chemical Analysis”

T. Sergeieva, T. A. Trevor, S. Okovytyy, B. Breit, M. Bickelhaupt, Chem. Eur. J. 2020, 26, 2342-2348. (link)
Abstract Image
 
249. “Asymmetric total Synthesis of (–)-Angustereine and (–)-Cuspareine via Rhodium-Catalyzed Hydroamination”

D. Berthold, B. Breit, Org. Lett. 2020, 22, 565-568. (link)
Abstract Image
 
248. “Ionic-liquid-modified CMK-3 as a support for the immobilization of molybdate opms (MoO42-): Heterogeneous nanocatalyst for selective oxidation of sulfindes and benzylic alcohols”

F. Hosseini-Eshbala, A. Sedrpoushan, B. Breit, F. Mohanazadeh, H. Veisi, Mat. Sci. Eng. C 2020, 11, 110577. (link)
Unlabelled Image
 
2019
247. “Rhodium-Catalyzed Diastereo- and Enantioselective Tandem Spirocyclization/Reduction of 3-Allenylindoles: Access to Functionalized Vinylic Spiroindolines”

C. P. Grugel, B. Breit, Org. Lett. 2019, 21, 9672-9676. (link)

 
246. “Synthesis of 2-(Isoquinolin-1-yl)prop-2-en-1-ones via Silver(I)-Catalzed One-Pot Tandem Reaction of ortho-Alkynylbenaldoximes with Propargylic Alcohols”

A. Nikbakht, S. Balalaie, B. Breit, Org. Lett. 2019, 21, 7645-7648. (link)

 
245. “Rhodium-catalyzed asymmetric intramolecular hydroarylation of allenes: access to functionalized benzocycles”

D. Berthold, J. Klett, B. Breit, Chem. Sci. 2019, 10, 10048-10052. (link)
 
Graphical abstract: Rhodium-catalyzed asymmetric intramolecular hydroarylation of allenes: access to functionalized benzocycles
 
244. “Visible‐Light‐Driven Intermolecular Reductive Ene–Yne Coupling by Iridium/Cobalt Dual Catalysis for C(sp3)−C(sp2) Bond Formation”

M. J. Gonzalez, B. Breit, Chem. Eur. J. 2019, 25, 15746-15750. (link)
 
image
 
243. “A domino reaction for generating β-aryl aldehydes from alkynes by substrate recognition catalysis”

W. Fang, F. Bauer, Y. Dong, B. Breit, Nat. Commun. 2019, 10, 4868. (link)
 

 
242. “Rhodium-Catalyzed Chemo-, Regio-, and Enantioselective Allylation of 2-Aminothiazoles with Terminal Allenes”

J. Zheng, B. Wörl, B. Breit, Eur. J. Org. 2019, 21, 5180-5182. (link)
 
image
 
241. “Rhodium-Catalyzed Enantioselective Cyclization of 3-Allenylindoles: Access to Functionalized Tetrahydrocarboazoles”

C. P. Grugel, B. Breit, Org. Lett. 2019, 21, 5798-5802. (link)
 
Abstract Image
 
240. “Rhodium-Catalyzed Asymmetric Intramolecular Hydroamination of Allenes”

D. Berthold, A. G. A. Geissler, S. Giofré, B. Breit, Angew. Chem. 2019, 131, 10099-10102. (link) Angew. Chem. Int. Ed. 2019, 58, 9994-9997. (link)
 
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239. “Rhodium-Catalyzed Parallel Kinetic Resolution of Racemic Internal Allenes Towards Enantiopure Allylic 1,3-Diketones”

L. Hilpert, B. Breit, Angew. Chem. 2019, 131, 10044-10048. (link) Angew. Chem. Int. Ed. 2019, 58, 9939-9943. (link)
 
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238. “Chemo-, Regio-, and Enantioselective Synthesis of Allylic Nitrones via Rhodium-Catalyzed Addition of Oximes to Allenes”

H. Wang, B. Breit, Chem. Commun. 2019, 55, 7619-7622. (link)
Graphical abstract: Chemo-, regio-, and enantioselective synthesis of allylic nitrones via rhodium-catalyzed addition of oximes to allenes
237. “Needle ball-like nanostructured mixed Cu-Ni-Co oxides: Synthesis, characterization and application to the selective oxidation of sulfides to sulfoxides”

F. Hosseini-Eshbala, A- Sdrpoushan, M. N. Dehdashti, B. Breit, F. Mohanazadeh, H. Veisi, Mat. Sci. Eng. C . 2019, 10, 109814. (link)

236. “A Rhodium-Catalyzed Cycloisomerization and Tandem Diels-Alder Reaction for Facile Access to Diverse Bicyclic and Tricyclic Heterocycles”

Y. Zhou, A. Nikbakht, F. Bauer, B. Breit, Chem. Sci. 2019, 10, 4805-4810. (link)
 
236
 
235. “Rhodium(I)-Catalyzed Allylation with Alkynes and Allenes”

A. B. Pritzius, B. Breit, in “Rhodium Catalysis in Organic Synthesis“ Ed. K. Tanaka, Wiley-VCH, Weinheim 2019, Chapter 6, pp 117-132. (link)
 
 
234. “Consice Total Synthesis of (-)-Vermiculine through a Rhodium-Catalyzed C2-symmetric Dimerization Strategy”

P. Steib, B. Breit, Chem. Eur. J. 2019, 25, 3532-3535. (link)
 
234
 
233. “Transition Metal Catalyzed Synthesis of syn- and anti--Vinyl-Lactames: Formal Total Synthesis of (-)-Cermizine C and (-)-Senepodine G”

J. P. Schmidt, B. Breit, Chem. Sci. 2019, 10, 3074-3079. (link)
 
233
 
2018
232. “Regiodivergent Hydroaminoalkylation of Alkynes and Allenes by a Combined Rhodium and Photoredox Catalytic System”

J. Zheng, B. Breit, Angew. Chem. 2018, 131, 3430-3435; (link) Angew. Chem. Int. Ed. 2018, 58, 3392-3397. (link)
 
232
 
231. “Palladium- and Rhodium-Catalyzed Dynamic Kinetic Resolution of Racemic Internal Allenes Towards Chiral Pyrazoles”

L. J. Hilpert, S. V. Sieger, A. M. Haydl, B. Breit, Angew. Chem. 2018, 131, 3416-3419; (link) Angew. Chem. Int. Ed. 2018, 58, 3378-3381. (link)
 
231
 
230. “Catalyst-free Hydrothiolation of Alkynes with Dithiocaramic Acids”

A. Ziyaei Halimehjani, B. Breit,Chem. Commun. 2019, 55, 1253-1255. (link)
 
230
 
229. “Palladium-Catalyzed Trisallylation of Azoles with Alkyne via sequential C(sp2)-H and C(sp3)-H Functionalization”

J. Zheng, F. Hosseini-Eshbala, Y.-X. Dong, B. Breit, Chem. Commun. 2019, 55, 624-627. (link)
 
229
 
2018
228. “Total Synthesis of (−)‐Cylindrocyclophane F: A Yardstick for Probing New Catalytic C−C Bond‐Forming Methodologies”

D. Berthold, B. Breit, Chem. Eur. J. 2018, 24 (63), 16770-16773. (link)
 
228
 
227. “Tandem Regioselective Hydroformylation‐Hydrogenation of Internal Alkynes Using a Supramolecular Catalyst”

W. Fang, B. Breit, Angew. Chem. 2018, 130, , 15033-15037; (link) Angew. Chem. Int. Ed. 2018, 57,14817-14821. (link)
227
 

226. “Rhodium‐Catalyzed Asymmetric Allylation of Malononitriles as Masked Acyl Cyanide with Allenes: Efficient Access to β,γ‐Unsaturated Carbonyls”

C. P. Grugel, B. Breit, , Chem. Eur. J. 2018, 24 , 15223-15226.; (link)
 
226
 
225. “Palladium-Catalyzed Stereoselective Cyclization of in Situ Formed Allenyl Hemiacetals: Synthesis of Rosuvastatin and Pitavastatin”

P. A. Spreider, B. Breit, Org. Lett. 2018, 20 (4), 3286-3290.; (link)
 
225
 
224. “Enantioselective Rhodium‐Catalyzed Dimerization of ω‐Allenyl Carboxylic Acids: Straightforward Synthesis of C2‐Symmetric Macrodiolides”

P. Steib, B. Breit, Angew. Chem. 2018, 130, , 6682-6686; (link) Angew. Chem. Int. Ed. 2018, 57,6572-6576. (link)
224
 

223. “Palladium-Catalyzed Direct C-H Allylation of Electron-Deficient Polyfluoroarenes with Alkynes”

J. Zheng, B. Breit, Org. Lett. 2018, 20 , 1866-1870.; (link)
 
223
 
222. “Functional Characterization of Three Specific Acyl-Coenzyme A Synthetases Involved in Anaerobic Cholesterol Degradation in Sterolibacterium denitrificans Chol1S”

M. Warnke, T. Jung, C. Jacoby, M. Agne, F. M. Feller, B. Philipp, W. Seiche, B. Breit, M. Boll, Appl. Environ. Microbiol. 2018, 84, e02721-17.; (link)

 
221. “Inducing Axial Chirality in a Supramolecular Catalyst”

K. M. Wenz, G. Leonhardt‐Lutterbeck, B. Breit, Angew. Chem. 2018, 130, 5194-5198 ; (link) Angew. Chem. Int. Ed. 2018, 57,5100-5104. (link)
221
 

220. “Rhodium-Catalyzed Enantioselective Decarboxylative Alkynylation of Allenes with Arylpropiolic Acids”

C. Grugel, B. Breit, Org. Lett. 2018, 20 (4), 1066–1069.; (link)
 
220
 
219. “Chemo-, Regio-, and Enantioselective Rhodium-Catalyzed Allylation of Triazoles with Internal Alkynes and Terminal Allenes”

D. Berthold, B. Breit, Org. Lett. 2018, 20 (3), 598–601.; (link)
 
219
 
218. “Selective Hydrogenation of Carboxylic Acids to Alcohols or Alkanes Employing a Heterogeneous Catalyst”

J. Ullrich, B. Breit , ACS Catal. 2018, 8, 785-789.; (link)
 
218
 
217. “Rhodium-Catalyzed Regio- and Enantioselective Addition of N-Hydroxyphthalimide to Allenes: A Strategy To Synthesize Chiral Allylic Alcohols”

Z. Liu, B. Breit, Org. Lett. 2018, 20 (1), 300-303.; (link)
 
217
 
2017
216. “Rhodium-Catalyzed Asymmetric N−H Functionalization of Quinazolinones with Allenes and Allylic Carbonates: The First Enantioselective Formal Total Synthesis of (−)-Chaetominine”

Y. Zhou, B. Breit, Chem. Eur. J. 2017, 23, 18156-18160.; (link)
 
216
215. “Beyond the BET Family: Targeting CBP/p300 with 4-Acyl Pyrroles”

M. Hügle, X. Lucas, D. Ostrovskyi, P. Regenass, S. Gerhardt, O. Einsle, M. Hau, M. Jung, B. Breit, S. Günther, D. Wohlwend, Angew. Chem. 2017, 129, 11466-11480 ; (link) Angew. Chem. Int. Ed. 2017, 56,11312–11325. (link)

215
 

214. “Alkynes as Electrophlic or Nucleophilic Allylmetal Precursors in Transition Metal Catalysis”

A. M. Haydl, B. Breit, T. Liang, M. J. Krische, Angew. Chem. 2017, 129, 11466-11480 ; (link) Angew. Chem. Int. Ed. 2017, 56,11312–11325. (link)

214 

213. “Rhodium-Catalyzed Regioselective Domino Azlactone-Alkyne Coupling/Aza-Cope Rearrangement: Facile Acess to 2-Allyl-3-oxazolin-5-ones and Trisubstituted Pyridines”

J. Kuang, S. Parveen, B. Breit, Angew. Chem. 2017, 129, 8542-8545 ; (link) Angew. Chem. Int. Ed. 2017, 56,8422-8425. (link)
212
 

212. “Chemo-, Regio-, and Enantioselective Rhodium-Catalyzed Allylation of Pyridazinones with Terminal Allenes”

S. Parveen, C. Li, A. Hassan, B. Breit, Org. Lett. 2017, 19, 2326-2329.; (link)
 
211
211. “Rhodium-catalyzed addition of sulfonyl hydrazides to allenes: regioselective synthesis of branched allylic sulfones”

V. Khakyzadeh, Y.-H. Wang, B. Breit, Chem. Commun. 2017, 53, 4966-4968.; (link)
 
210
210. “Transition-Metal-Catalyzed Regiodivergent and Stereoselective Access to Branched and Linear Allylated 4-Pyridones”

J. Schmidt, C. Li, B. Breit, Chem. Eur. J. 2017, 23, 6531-6534; (link)
 
209
209. “Regio- and Enantioselective Rhodium-Catalyzed Addition of 1,3-Diketones to Allenes: Construction of Asymmetric Tertiary and Quaternary All Carbon Centers”

T. M. Beck, B. Breit, Angew. Chem. 2017, 129, 1929-1933 ; (link) Angew. Chem. Int. Ed. 2017, 56, 1903-1907. (link)
208
 

208. “Enantioselective and Regiodivergent Addition of Purines to Terminal Allenes: Synthesis of Abacavir”

N. Thieme, B. Breit, Angew. Chem. 2017, 129, 1542-1546 ; (link) Angew. Chem. Int. Ed. 2017, 56, 1520-1524. (link)
207a
 

207. “The Total Synthesis of Epothilone D as a Yardstick for Probing New Methodologies”

A. Haydl, B. Breit , Chem. Eur. J. 2017, 23, 541-545; (link)
 206

2016
206. “Preparation data of the bromodomains BRD3(1), BRD3(2), BRD4(1), and BRPF1B and crystallization of BRD4(1)-inhibitor complexes”

M. Hügle, X. Lucas, G. Weitzel, D. Ostrovskyi, B. Breit, S. Gerhardt, S. Schmidtkunz, M. Jung, R. Schüle, O. Einsle, S. Günther, D. Wohlwend, Data Brief. 2016, 93, 1370-1374; (link)
 

205. “Regioselective Rhodium-Catalyzed Addition of β-Keto Esters, β-Keto Amides and 1,3-Diketones to Internal Alkynes”

T. M. Beck, B. Breit, Eur. J. Org. Chem. 2016, 93, 5839-5844; (link)
 205

204. “Rhodium-Catalyzed Diastereoselective Cyclization of Allenylsufolnylcarbamates: A Stereodivergent Approach to 1,3-Aminoalcohol Derivatives”

P. Spreider, A. Haydl, M. Heinrich, B. Breit Angew. Chem. 2016, 128, 15798-15802 ; (link) Angew. Chem. Int. Ed. 2015, 55, 15569-15573. (link)
204 

203. “Rhodium-Catalyzed Addition of Carboxylic Acids to Terminal Alkynes towards Z-Enol Esters ”

S. Ganss, J. Pedroni, A. Lumbroso, G. Leonhardt-Lutterbeck, A. Meißner, S. Wei, H.-J. Drexler, D. Heller, B. Breit, Org. Synth. 2016, 93, 367-384; (link)
 203

202. “Rhodium-Catalyzed Dynamic Kinetic Asymmetric Allylation of Phenols and 2-Hydroxypyridines”

P.C. Li, B. Breit, Chem. Eur. J. 2016, 22, 14655-14663 ; (link)
 202

201. “Tofacitinib and analogs as inhibitors of the histone kinase PRK1 (PKN1)”

D. Ostrovskyi, T. Rumpf, J. Eib, A. Lumbroso, I. Slynko, S. Klaeger, S. Heinzlmeir, M. Forster, M. Gehringer, E. Pfaffenrot, S. M. Bauer, K. Schmidtkunz, S. Wenzler, E. Metzgr, B. Kuster, R. Schüle, W. Sippl, B. Breit, M. Jung, Future Med. Chem. 2016, 8, 1537-1551 ; (link)
 201

200. “Branching Out: Rhodium-Catalyzed Allylation with Alkynes and Allenes”

P. Koschker, B. Breit, Acc. Chem. Res. 2016, 49, 1524-1536 ; (link)
 200

199. “Enantioselective Rhodium-Catalyzed Atom-Economical Macrolactonization”

S. Ganss, B. Breit, Angew. Chem. 2016, 128, 9890-9894 ; (link) Angew. Chem. Int. Ed. 2015, 55, 9738-9742. (link)
 199

198. “Rhodium-Catalyzed Enantioselective Intermolecular Hydroalkoxylation of Allenes and Alkynes with Alcohols Leading to Branched Allylic Ethers”

Z. Liu, B. Breit, Angew. Chem. 2016, 128, 8580–8583 ; (link) Angew. Chem. Int. Ed. 2016, 55, 8440-8443. (link)
 198

197. “Stereodivergent and Protecting-Group-Free Synthesis of the Helicascolide Family: A Rhodium-Catalyzed Atom-Economical Lactonization Strategy”

A. Haydl, D. Berthold, P. A. Spreider, B. Breit, Angew. Chem. 2016, 128, 5859–5863 ; (link) Angew. Chem. Int. Ed. 2015, 55, 5765–5769. (link)
 197

196. “Regioconvergent and Enantioselective Rhodium-Catalyzed Hydroamination of Internal and Terminal Alkynes: A Highly Flexible Access to Chiral Pyrazoles”

A. M. Haydl, L. J. Hilpert, B. Breit, Chem. Eur. J. 2016, 22, 6547-6551 ; (link)
 196

195. “Rhodium-Catalyzed Chemo- and Regioselective Decarboxylative Addition of β-Ketoacids to Alkynes”

C. Li, C. P. Grugel, B. Breit, Chem. Commun. 2016, 52, 5840-5843 ; (link)
 195

194. “Asymmetric Synthesis of Allylic Amines via Hydroamination of Allenes with Benzophenone Imine”

K. Xu, Y.-H. Wang, V. Khakyzadeh, Chem. Sci. 2016, 7, 3313-3316 (link)
 194

193. “4-Acyl Pyrrole Derivatives Yield Novel Vectors for Designing Inhibitors of the Acetyl-Lysine Recognition Site of BRD4((1)”

M. Hügle, X. Lucas, G. Weitzel, D. Ostrovskyi, B. Breit, S. Gerhard, O. Einsle, S. Günther, D. Wohlwend J. Med. Chem. 2016, 59, 1518–1530 ; (link)
 193

192. “Regioselective Rhodium-Catalyzed Addition of 1,3-Dicarbonyl Compounds to Terminal Alkynes”

T. M. Beck, B. Breit, Org. Lett. 2016, 18, 124–127 ; (link)
 192

2015
191. “Z-Selective Hydrothiolation of Racemic 1,3-Disubstituted Allenes: An Atom-Economic Rhodium-Catalyzed Dynamic Kinetic Resolution”

A. B. Pritzius, B. Breit, Angew. Chem. 2015, 127, 16044–16048; (link) Angew. Chem. Int. Ed. 2015, 54, 15818–15822. (link)
 189.png

190. “Atom-Economical Dimerization Strategy by the Rhodium-Catalyzed Addition of Carboxylic Acids to Allenes: Protecting-Group-Free Synthesis of Clavosolide A and Late-Stage Modification”

A. Haydl, B. Breit, Angew. Chem. 2015, 127, 15750–15754 ; (link) Angew. Chem. Int. Ed. 2015, 54, 15530–15534. (link)
 190

189. “Cuticular Hydrocarbon Pheromones for Social Behavior and Their Coding in the Ant Antenna”

K. R. Sharma, B. L. Enzmann, Y. Schmidt, et al. B. Breit, J. Liebig, A. Ray, Cell Reports, 2015 (link)

189ameise
 

188. “Asymmetric synthesis of N-allylic indoles via regio- and enantioselective allylation of aryl hydrazines”

K. Xu, T. Gilles, B. Breit, Nat. Commun., 2015 6, 7616; (link)
187abstract

187. “ Enantioselective formation of tertiary and quaternary allylic C–N bonds via allylation of tetrazoles ”

K. Xu, W. Raimondi, T. Bury, B. Breit, Chem. Commun., 2015 51, 10861-00863; (link)
188abstract

186. “Regio- and Enantioselective Synthesis of N-Substituted Pyrazoles by Rhodium-Catalyzed Asymmetric Addition to Allenes”

A. M. Haydl, K. Xu, B. Breit, Angew. Chem. 2015, 127, 7255-7259; (link) Angew. Chem. Int. Ed. 2015, 54, 7149-7153. (link)
186abstract 

185. “Rhodium-Catalyzed Hydroformylation of 1,1-Disubstituted Allenes Employing the Self-Assembling 6-DPPon System”

A. Köpfer, B. Breit, Angew. Chem. 2015, 127, 7017-7021; (link) Angew. Chem. Int. Ed. 2015, 54, 6913-6917. (link)
185abstract
 

184. “Paraformaldehyde and Methanol as C1 Feedstocks in Metal-Catalyzed C-C Couplings of π-Unsaturated Reactants: Beyond Hydroformylation”

B. Sam, B. Breit, M. J. Krische, Angew. Chem. 2015, 127, 3317-3325; (link) Angew. Chem. Int. Ed. 2015, 54, 3267-3274. (link)
 184abstract

183. “Asymmetric Rhodium-Catalyzed Addition of Thiols to Allenes: Synthesis of Branched Allylic Thioethers and Sulfones”

A. B. Pritzius, B. Breit, Angew. Chem. 2015, 1273164-3168; (link) Angew. Chem. Int. Ed. 2015, 54, 3121-3125. (link)
Asymmetric Rhodium-Catalyzed Addition of Thiols to Allenes: Synthesis of Branched Allylic Thioethers and Sulfones

182. “Structural Characterization of O- and C-Glycosylating Variants of the Landomycin Glycosyltransferase LanGT2”

H. K. Tam, J. Härle, S. Gerhardt, J. Rohr, G. Wang, J. S. Thorson, A. Bigot, M. Lutterbeck, W. Seiche,B. Breit, A Bechthold, O. Einsle, Angew. Chem. 2015, 127, 2853-2857; (link) Angew. Chem. Int. Ed. 2015, 54, 2811-2815. (link)
182abstract

181. “Enantioselective Redox-Neutral Rh-Catalyzed Coupling of Terminal Alkynes with Carboxylic Acids Toward Branched Allylic Esters”

P. Koschker, M. Kähny, B. Breit, J. Am. Chem. Soc., 2015 137 (8), 3131-3137; (link)
181abstract

180. “Probing o-Diphenylphosphanyl Benzoate (o-DPPB)-Directed C–C Bond Formation: Total Synthesis of Dictyostatin”

S. Wünsch, B. Breit, Chem. Eur. J. 2015, 21, 2358–2363; (link)
180abstract

179. “Easily Accessible TADDOL-Derived Bisphosphonite Ligands: Synthesis and Application in the Asymmetric Hydroformylation of Vinylarenes”

S. Allmendinger, H. Kinuta, B. Breit, Adv. Synth. Catal. 2015, 357, 41-45; (link)
179abstract

178. “Full kinetic analysis of a rhodium-catalyzed hydroformylation: beyond the rate-limiting step picture”

U. Gellrich, T. Koslowski, B. Breit, Cat. Sci. Technol., 2015 5 , 129-133; (link)
178abstract

2014
177. “Direct Transformation of Terminal Alkynes to Branched Allylic Sulfones”

K. Xu, V. Khakyzadeh, T. Bury, B. Breit, J. Am. Chem. Soc., 2014 136 , 16124-16127; (link)
177abstract

176. “Rhodium-Catalyzed Chemo-, Regio-, and Enantioselective Addition of 2-Pyridones to Terminal Allenes”

C. Li, M. Kähny, B. Breit, Angew. Chem. 2014, 126, 14000-14004; (link) Angew. Chem. Int. Ed. 2014, 53, 13780-13784. (link)
176abstract

175. “New phosphorus self-assembling ligands for the tandem hydroformylation-Wittig olefination reaction of homoallylic alcohols – A key step for stereoselective pyran synthesis”

Q. Ruan, L. Zhou, B. Breit, Cat. Commun. 2014, 53, 87*90; (link)
175abstract

174. “Unlocking the N2 Selectivity of Benzotriazoles: Regiodivergent and Highly Selective Coupling of Benzotriazoles with Allenes”

K. Xu, N. Thieme, B. Breit, Angew. Chem. 2014, 126, 7396-7399; (link) Angew. Chem. Int. Ed. 2014, 53, 7268-7271; (link)
174abstract

173. “Efficient Synthesis of New Fluorinated Building Blocks by means of Hydroformylation”

L. Fanfoni, L. Diab, T. Smejkal, B. Breit, Chimia 2014, 19, 68, 371-377; (link)
172. “Mechanistic insight into the ruthenium-catalysed anti-Markovnikov hydration of alkynes using a self-assembled complex: a crucial role for ligand-assisted proton shuttle processes”

B. Breit, U. Gellrich, T. Li, J. M. Lynam, L. M. Miller, N. E. Pridmore, J. M. Slattery, A. C. Whitwood, Dalton Trans. 2014, 43, 11277-11285.; (link)
172abstract

171. “Tandem Regioselective Rhodium-Catalyzed Hydroformylation-Enantioselective Aminocatalytic anti-Mannich Reaction”

S. Diezel, B. Breit, Synthesis. 2014, 46, 1311-1320; (link)
171abstract

170. “Hydroformylation and Related Carbonylation Reactions of Alkenes, Alkynes, and Allenes”

B. Breit and L. Diab, In: Gary A. Molander and Paul Knochel (eds.), Comprehensive Organic Synthesis, 2nd Edition, Vol 4, Oxford: Elsevier 2014, pp. 995-1053; (link)
169. “Atom-Economic, Regiodivergent, and Stereoselective Coupling of Imidazole Derivatives with Terminal Allenes”

K. Xu, N. Thieme, B. Breit, Angew. Chem. 2014, 126, 2194-2197; (link) Angew. Chem. Int. Ed. 2014, 53, 2162-2165. (link)
169abstract

168. “Total Synthesis of (18S)- and (18R)-Homolargazole by Rhodium-Catalyzed Hydrocarboxylation”

C. Schotes, D. Ostrovskyi, J. Senger, K. Schmidtkunz, M. Jung, B. Breit, Chem. Eur. J. 2014, 20, 2164-2168; (link)
168abstract

167. “Mechanistic Investigations of the Rhodium Catalyzed Propargylic CH Activation”

U. Gellrich, A. Meißner, A. Steffani, M. Kähny, H.-J. Drexler, D. Heller, D. A. Plattner, B. Breit, J. Am. Chem. Soc. 2014, 136, 1097-1104; (link)
167abstract

166. “Rhodium-Catalyzed Chemo- and Regioselective Decarboxylative Addition of β-Ketoacids to Allenes: Efficient Construction of Tertiary and Quaternary Carbon Centers”

C. Li, B. Breit, J. Am. Chem. Soc., 2014, 136 (3), 862–865; (link)
166abstract
 
2013
165. “Realistic Energy Surfaces for Real World Systems: an IMOMO CCSD(T):DFT scheme for the Rhodium Catalyzed Hydroformylation with the 6-DPPon ligand”

U. Gellrich, D. Himmel, M. Meuwly, B. Breit, Chem. Eur. J. 2013, 19, 16272-16281; (link)
164. “Tandem decarboxylative hydroformylation-hydrogenation reaction of α,β-unsaturated carboxylic acids toward aliphatic alcohols under mild conditions employing a supramolecular catalyst system”

L. Diab, U. Gellrich, B. Breit, Chem. Commun. 2013, 49,9737-9739; (link)
163. “Tandem Hydroformylation/Biginelli Reaction”

D. Fuchs, M. Nasr-Esfahani, L. Diab, T. Smejkal, B. Breit, Synlett 2013, 13, 1657-1662; (link)
162. “Room Temperatur Ambient Pressure (RTAP)-Hydroformylation in Water Using a Self-Assembling Ligand”

A. T. Straub, M. Otto, I. Usui, B. Breit, Adv. Synth. Cat. 2013, 75, 2071-2075; (link)
161. “A Systematic Investigation of Coinage Metal Carbonyl Complexes Stabilized by Fluorinated Alkoxy Aluminates”

J. Schaefer, A. Kraft, S. Reininger, G. Santiso-Quinones, D. Himmel, N. Trapp, U. Gellrich, B. Breit, I. Krossing Chem. Eur. J. 2013, 19, 12468-12485; (link)
160. “Development of an Improved Rhodium-Catalyst for Z-selective anti-Markovnikov Addition of Carboxylic Acids to Terminal Alkynes”

S. Wei, J. Pedroni, A. Meißner, A. Lumbroso, H.-J. Drexler, D. Heller, B. Breit, Chem. Eur. J. 2013, 19, 12067-12076; (link)
159. “Bernhard Breit – Author Profile”

B. Breit, Angew. Chem. 2013, 125, 10072-10073; (link) Angew. Chem. Int. Ed. 2013, 52, 9888-9889; (link)
158. “Rhodium-catalyzed hydroformylation of alkynes employing a self-assembling ligand system”

V. Agabekov, W. Seiche, B. Breit, Chem. Sci. 2013, 4, 2418-2422; (link)
157. “Regiodivergent reductive coupling of 2-substituted dienes to formaldehyde employing ruthenium or nickel catalyst: hydrohydroxymethylation via transfer hydrogenation”

A. Köpfer, B. Sam, B. Breit, M. Krische, Chem. Sci. 2013, 4, 1876-1880; (link)
156. “Catalytic Hydrogenation of Amides to Amines under Mild Conditions”

M. Stein, B. Breit, Angew. Chem. 2013, 125, 2287-2290; (link) Angew. Chem. Int. Ed. 2013, 52, 2231-2234; (link)
155. “Nachruf Horst Prinzbach (1931-2012)”

B. Breit, R. Brückner, Nachr. Chem. 2013, 61, 163;
154. “Catalytic Asymmetric Synthesis of Allylic Alcohols and Derivatives and their Applications in Organic Synthesis”

A. Lumbroso, M. L. Cooke, B. Breit, Angew. Chem. 2013, 125, 1942-1986(link); Angew. Chem. Int. Ed. 2013, 52, 1890-1932; (link)
153. “Potent Inhibitors of Malarial Aspartic Proteases, the Plasmepsins, by Hydroformylation of Substituted 7-Azanorbornenes”

V. Aureggi, V. Ehmke, J. Wieland, W. B. Schweizer, B. Bernet, D. Bur, S. Meyer, M. Rottmann, C. Freymond, R. Brun, B. Breit, F. Diederich, Chem. Eur. J. 2013, 19, 155-164; (link)


2012
152. “Hydrogen-Bond and Solvent Dynamics in Transition Metal Complexes: A Combined Simulation and NMR-Investigation”

J. Huang, D. Häussinger, U. Gellrich, W. Seiche, B. Breit, M. Meuwly, J. Phys. Chem. B 2012, 116, 14406-14415 null null; (link)
151. “Dicarbonyl(acetylacetonato) Rhodium(I)”

B. Breit, Encyclopedia of Reagents for Organic Synthesis, Eds. D. Crich, A Charette, P. L. Fuchs, T. Rovis, first update 2012, John Wiley & Sons Ltd.
150. "Enantioselective Rhodium-Catalyzed Synthesis of Branched Allylic Amines by Intermolecular Hydroamination of Terminal Allenes"

M. L. Cooke, Kun Xu, B. Breit, Angew. Chem. 2012, 124, 11034-11037; (link) Angew. Chem. Int. Ed. 2012, 51, 10876-10879. (link)
149. "Mechanistic Insights into a Supramolecular Self-Assembling Catalyst System: Evidence for Hydrogen-Bonding during Rhodium-Catalyzed Hydroformylation"

U. Gellrich, W. Seiche, M. Keller, B. Breit, Angew. Chem. 2012, 124, 11195-11200; (link) Angew. Chem. Int. Ed. 2012, 51, 11033-11038. (link)
148.
"Assignment of Relative Configuration of Desoxypropionates by 1H NMR Spectroscopy: Method Development, Proof of Principle by Asymmetric Total Synthesis of Xylarinic Acid A and Applications"

Y. Schmidt, K. Lehr, L. Colas, B. Breit, Chem. Eur. J. 2012, 18, 7071-7081.(link)
147.
"Preparation of Alkylmagnesium Reagents from Alkenes through Hydroboration and Boron-Magnesium Exchange"

M. Reichle, B. Breit, Angew. Chem. 2012, 124, 5828-5832; (link) Angew. Chem. Int. Ed. 2012, 51, 5730-5734. (link) highlighted in SynFacts as Synfact of the Month September (link)
146.
"Tandem Rhodium-Catalyzed Hydroformylation-Hydrogenation of Alkenes by Employing a Cooperative Ligand System"

D. Fuchs, G. Rousseau, L. Diab, U. Gellrich, B. Breit, Angew. Chem. 2012, 124, 2220-2224; (link) Angew. Chem. Int. Ed. 2012, 51, 2178-2182. (link)
145.
"Atom Economic Macrolactonization and Lactonization via Redox-Neutral Rhodium-Catalyzed Coupling of Terminal Alkynes with Carboxylic Acids"

A. Lumbroso, N. Abermil, B. Breit, Chem. Sci. 2012, 3, 789-793. (link)


2011
144.
"Enantioselective Synthesis of Branched Allylic Esters via Rhodium-Catalyzed Coupling of Allenes with Carboxylic Acids"

P. Koschker, A. Lumbroso, B. Breit, J. Am. Chem. Soc. 2011, 133, 20746-20749. (link)
143.
"Rhodium(I)-Catalyzed 1,4-Addition of Arylboronic Acids to Acrylic Acids in Water: One-Step Preparation of 3-Arylpropionic Acids"

N. R. Vautravers, B. Breit, Synlett 2011, 2517-2520. (link)
142.
"Stereoselective and Diversity-Oriented Synthesis of Trisubstituted Allylic Alcohols and Amines"

Y. Schmidt, B. Breit, Chem. Eur. J. 2011, 17, 11789-11796. (link)
141.
"Stereoselective Synthesis of Trisubstituted Olefins by a Directed Allylic Substitution Strategy"

Y. Schmidt, B. Breit, Chem. Eur. J. 2011, 17, 11780-11788. (link)
140.
"Phosphorylation of Tip60 by GSK-3 Determines the Induction of PUMA and Apoptosis by p53"

C. Charvet, M. Wissler, P. Brauns-Schubert, S.J. Wang, Y. Tang, F. C. Sigloch, H. Mellert, M Brandenburg, S. E. Lindner, B. Breit, D. R. Green, S. B. McMahon, C. Borner, W. Gu, U. Maurer, Molecular Cell 2011, 42, 584-596. (link)
139.
"Formation of Quaternary Carbon Centers by Highly Regioselective Hydroformylation with Catalytic Amounts of a Reversibly Bound Directing Group"

Y. Ueki, H. Ito, I. Usui, B. Breit, Chem Eur. J. 2011, 17, 8555-8558. (link)
138.
"Divergent Regioselectivity in the Synthesis of Trisubstituted Allylic Alcohols by Nickel- and Ruthenium-Catalyzed Alkyne Hydroxymethylation with Formaldehyde"

C. C. Bausch, R. L. Patman, B. Breit, M. J. Krische, Angew. Chem. 2011, 123, 5805-5808; (link) Angew. Chem. Int. Ed. 2011, 50, 5687-5690. (link)
137.
"Inter- and Intramolecular Hydroacylation of Alkenes Employing a Bifunctional Catalyst System"

N. R. Vautravers, D. D. Regent, B. Breit, Chem. Commun. 2011, 6635-6637. (link)
136.
"Removable Directing Groups in Organic Synthesis and Homogeneous Catalysis"

G. Rousseau, B. Breit, Angew. Chem. 2011, 123, 2498-2543; (link) Angew. Chem. Int. Ed. 2011, 50, 2450-2494. (link)
135.
"Redox-Neutral Atom Economic Rhodium-Catalyzed Coupling of Terminal Alkynes with Carboxylic Acids Toward Branched Allylic Esters"

A. Lumbroso, P. Koschker, N. R. Vautravers, B. Breit, J. Am. Chem. Soc. 2011, 133, 2386-2389. (link)
134.
"Iron Nanoparticles Supported on Chemically-Derived Graphene: Catalytic Hydrogenation with Magnetic Catalyst Separation"

M. Stein, J. Wieland, P. Steurer, F. Tölle, R. Mülhaupt, B. Breit, Adv. Synth. Cat. 2011, 353, 523-527. (link)
133.
"Diastereoselective Hydroformylation of 2,5-Cyclohexadienyl-1-carbinols with Catalytic Amounts of a Reversibly Bound Directing Group"

I. Usui, K. Nomura, B. Breit, Org. Lett. 2011, 13, 612-615. (link)
132.
"Ligand Self-Assembling through Complementary Hydrogen Boning in the coordination Sphere of a Transition Metal Center: The Phosphanylpyridin-2(1H)-one System"

U. Gellrich, J. Huang, W. Seiche, M. Keller, M. Meuwly, B. Breit, J. Am. Chem. Soc. 2011, 133, 964-975. (link)

 


 

 

 

 

 

 

 

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