Publications 2011-2020
2020 | |
254. | “Rhodium-Catalyzed Cyclization of Terminal and Internal Allenols: An Atom-Economic and Highly Stereoselective Access Towards Tetrahydropyrans” |
Johannes P. Schmidt, B. Breit, Angew. Chem. 2020, 132, 23691-23696. (link)
Angew. Chem. Int. Ed. 2020, 59, 23485-23490.
(link)
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253. | “4-Acyl Pyrroles as Dual BET-BRD7/9 Bromodomain Inhibitors Address BETi Insensitive Human Cancer Cell Lines” |
M. Hügle, P. Regenass, R. Warstat, M. Hau, K. Schmidtkunz, X. Lucas, D. Wohlwend, O. Einsle, M. Jung, B. Breit, S. Günther, Eur. J. Org. Chem. 2020, 6081-6084. (link)
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252. | “Amino Acid-Based Dithiocarbamates as Efficient Intermediates for Diversity-Oriented Synthesis of Thiazoles” |
A. Z. Halimehjani, M. Khalesi, B. Breit, Eur. J. Org. Chem. 2020, 6081-6084. (link)
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251. | “Synthesis of Thailandepsin B Pseudo-Natural Products: Access to New Highly Potent HDAC Inhibitors via Late-Stage Modification” |
J. Brosowsky, M. Lutterbeck, A. Liebich, M. Keller, D. Herp, A. Vogelmann, M. Jung, B. Breit, Chem. Eur. J. 2020, 26, 16241-16245. (link)
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250. | “Ligand-Mediated Regioselective Rhodium-Catalyzed Benzotriazole-Allene Coupling: Mechanistic Exploration and Quantum Chemical Analysis” |
T. Sergeieva, T. A. Trevor, S. Okovytyy, B. Breit, M. Bickelhaupt, Chem. Eur. J. 2020, 26, 2342-2348. (link)
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249. | “Asymmetric total Synthesis of (–)-Angustereine and (–)-Cuspareine via Rhodium-Catalyzed Hydroamination” |
D. Berthold, B. Breit, Org. Lett. 2020, 22, 565-568. (link)
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248. | “Ionic-liquid-modified CMK-3 as a support for the immobilization of molybdate opms (MoO42-): Heterogeneous nanocatalyst for selective oxidation of sulfindes and benzylic alcohols” |
F. Hosseini-Eshbala, A. Sedrpoushan, B. Breit, F. Mohanazadeh, H. Veisi, Mat. Sci. Eng. C 2020, 11, 110577. (link)
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2019 | |
247. | “Rhodium-Catalyzed Diastereo- and Enantioselective Tandem Spirocyclization/Reduction of 3-Allenylindoles: Access to Functionalized Vinylic Spiroindolines” |
C. P. Grugel, B. Breit, Org. Lett. 2019, 21, 9672-9676. (link)
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246. | “Synthesis of 2-(Isoquinolin-1-yl)prop-2-en-1-ones via Silver(I)-Catalzed One-Pot Tandem Reaction of ortho-Alkynylbenaldoximes with Propargylic Alcohols” |
A. Nikbakht, S. Balalaie, B. Breit, Org. Lett. 2019, 21, 7645-7648. (link)
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245. | “Rhodium-catalyzed asymmetric intramolecular hydroarylation of allenes: access to functionalized benzocycles” |
D. Berthold, J. Klett, B. Breit, Chem. Sci. 2019, 10, 10048-10052. (link)
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244. | “Visible‐Light‐Driven Intermolecular Reductive Ene–Yne Coupling by Iridium/Cobalt Dual Catalysis for C(sp3)−C(sp2) Bond Formation” |
M. J. Gonzalez, B. Breit, Chem. Eur. J. 2019, 25, 15746-15750. (link)
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243. | “A domino reaction for generating β-aryl aldehydes from alkynes by substrate recognition catalysis” |
W. Fang, F. Bauer, Y. Dong, B. Breit, Nat. Commun. 2019, 10, 4868. (link)
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242. | “Rhodium-Catalyzed Chemo-, Regio-, and Enantioselective Allylation of 2-Aminothiazoles with Terminal Allenes” |
J. Zheng, B. Wörl, B. Breit, Eur. J. Org. 2019, 21, 5180-5182. (link)
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241. | “Rhodium-Catalyzed Enantioselective Cyclization of 3-Allenylindoles: Access to Functionalized Tetrahydrocarboazoles” |
C. P. Grugel, B. Breit, Org. Lett. 2019, 21, 5798-5802. (link)
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240. | “Rhodium-Catalyzed Asymmetric Intramolecular Hydroamination of Allenes” |
D. Berthold, A. G. A. Geissler, S. Giofré, B. Breit, Angew. Chem. 2019, 131, 10099-10102. (link)
Angew. Chem. Int. Ed. 2019, 58, 9994-9997.
(link)
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239. | “Rhodium-Catalyzed Parallel Kinetic Resolution of Racemic Internal Allenes Towards Enantiopure Allylic 1,3-Diketones” |
L. Hilpert, B. Breit, Angew. Chem. 2019, 131, 10044-10048. (link)
Angew. Chem. Int. Ed. 2019, 58, 9939-9943.
(link)
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238. | “Chemo-, Regio-, and Enantioselective Synthesis of Allylic Nitrones via Rhodium-Catalyzed Addition of Oximes to Allenes” |
H. Wang, B. Breit, Chem. Commun. 2019, 55, 7619-7622. (link) |
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237. | “Needle ball-like nanostructured mixed Cu-Ni-Co oxides: Synthesis, characterization and application to the selective oxidation of sulfides to sulfoxides” |
F. Hosseini-Eshbala, A- Sdrpoushan, M. N. Dehdashti, B. Breit, F. Mohanazadeh, H. Veisi, Mat. Sci. Eng. C . 2019, 10, 109814. (link) |
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236. | “A Rhodium-Catalyzed Cycloisomerization and Tandem Diels-Alder Reaction for Facile Access to Diverse Bicyclic and Tricyclic Heterocycles” |
Y. Zhou, A. Nikbakht, F. Bauer, B. Breit, Chem. Sci. 2019, 10, 4805-4810. (link)
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235. | “Rhodium(I)-Catalyzed Allylation with Alkynes and Allenes” |
A. B. Pritzius, B. Breit, in “Rhodium Catalysis in Organic Synthesis“ Ed. K. Tanaka, Wiley-VCH, Weinheim 2019, Chapter 6, pp 117-132. (link)
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234. | “Consice Total Synthesis of (-)-Vermiculine through a Rhodium-Catalyzed C2-symmetric Dimerization Strategy” |
P. Steib, B. Breit, Chem. Eur. J. 2019, 25, 3532-3535. (link)
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233. | “Transition Metal Catalyzed Synthesis of syn- and anti--Vinyl-Lactames: Formal Total Synthesis of (-)-Cermizine C and (-)-Senepodine G” |
J. P. Schmidt, B. Breit, Chem. Sci. 2019, 10, 3074-3079. (link)
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232. | “Regiodivergent Hydroaminoalkylation of Alkynes and Allenes by a Combined Rhodium and Photoredox Catalytic System” |
J. Zheng, B. Breit, Angew. Chem. 2019, 131, 3430-3435; (link) Angew. Chem. Int. Ed. 2019, 58, 3392-3397.
(link)
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231. | “Palladium- and Rhodium-Catalyzed Dynamic Kinetic Resolution of Racemic Internal Allenes Towards Chiral Pyrazoles” |
L. J. Hilpert, S. V. Sieger, A. M. Haydl, B. Breit, Angew. Chem. 2019, 131, 3416-3419; (link) Angew. Chem. Int. Ed. 2019, 58, 3378-3381.
(link)
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230. | “Catalyst-free Hydrothiolation of Alkynes with Dithiocaramic Acids” |
A. Ziyaei Halimehjani, B. Breit,Chem. Commun. 2019, 55, 1253-1255. (link)
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229. | “Palladium-Catalyzed Trisallylation of Azoles with Alkyne via sequential C(sp2)-H and C(sp3)-H Functionalization” |
J. Zheng, F. Hosseini-Eshbala, Y.-X. Dong, B. Breit, Chem. Commun. 2019, 55, 624-627. (link)
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2018 | |
228. | “Total Synthesis of (−)‐Cylindrocyclophane F: A Yardstick for Probing New Catalytic C−C Bond‐Forming Methodologies” |
D. Berthold, B. Breit, Chem. Eur. J. 2018, 24 (63), 16770-16773. (link)
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227. | “Tandem Regioselective Hydroformylation‐Hydrogenation of Internal Alkynes Using a Supramolecular Catalyst” |
W. Fang, B. Breit, Angew. Chem. 2018, 130, , 15033-15037; (link) Angew. Chem. Int. Ed. 2018, 57,14817-14821.
(link) |
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226. | “Rhodium‐Catalyzed Asymmetric Allylation of Malononitriles as Masked Acyl Cyanide with Allenes: Efficient Access to β,γ‐Unsaturated Carbonyls” |
C. P. Grugel, B. Breit, , Chem. Eur. J. 2018, 24 , 15223-15226.; (link)
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225. | “Palladium-Catalyzed Stereoselective Cyclization of in Situ Formed Allenyl Hemiacetals: Synthesis of Rosuvastatin and Pitavastatin” |
P. A. Spreider, B. Breit, Org. Lett. 2018, 20 (4), 3286-3290.; (link)
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224. | “Enantioselective Rhodium‐Catalyzed Dimerization of ω‐Allenyl Carboxylic Acids: Straightforward Synthesis of C2‐Symmetric Macrodiolides” |
P. Steib, B. Breit, Angew. Chem. 2018, 130, , 6682-6686; (link) Angew. Chem. Int. Ed. 2018, 57,6572-6576.
(link) |
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223. | “Palladium-Catalyzed Direct C-H Allylation of Electron-Deficient Polyfluoroarenes with Alkynes” |
J. Zheng, B. Breit, Org. Lett. 2018, 20 , 1866-1870.; (link)
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222. | “Functional Characterization of Three Specific Acyl-Coenzyme A Synthetases Involved in Anaerobic Cholesterol Degradation in Sterolibacterium denitrificans Chol1S” |
M. Warnke, T. Jung, C. Jacoby, M. Agne, F. M. Feller, B. Philipp, W. Seiche, B. Breit, M. Boll, Appl. Environ. Microbiol. 2018, 84, e02721-17.; (link)
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221. | “Inducing Axial Chirality in a Supramolecular Catalyst” |
K. M. Wenz, G. Leonhardt‐Lutterbeck, B. Breit, Angew. Chem. 2018, 130, 5194-5198 ; (link) Angew. Chem. Int. Ed. 2018, 57,5100-5104.
(link) |
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220. | “Rhodium-Catalyzed Enantioselective Decarboxylative Alkynylation of Allenes with Arylpropiolic Acids” |
C. Grugel, B. Breit, Org. Lett. 2018, 20 (4), 1066–1069.; (link)
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219. | “Chemo-, Regio-, and Enantioselective Rhodium-Catalyzed Allylation of Triazoles with Internal Alkynes and Terminal Allenes” |
D. Berthold, B. Breit, Org. Lett. 2018, 20 (3), 598–601.; (link)
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218. | “Selective Hydrogenation of Carboxylic Acids to Alcohols or Alkanes Employing a Heterogeneous Catalyst” |
J. Ullrich, B. Breit , ACS Catal. 2018, 8, 785-789.; (link)
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217. | “Rhodium-Catalyzed Regio- and Enantioselective Addition of N-Hydroxyphthalimide to Allenes: A Strategy To Synthesize Chiral Allylic Alcohols” |
Z. Liu, B. Breit, Org. Lett. 2018, 20 (1), 300-303.; (link)
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2017 | |
216. | “Rhodium-Catalyzed Asymmetric N−H Functionalization of Quinazolinones with Allenes and Allylic Carbonates: The First Enantioselective Formal Total Synthesis of (−)-Chaetominine” |
Y. Zhou, B. Breit, Chem. Eur. J. 2017, 23, 18156-18160.; (link)
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215. | “Beyond the BET Family: Targeting CBP/p300 with 4-Acyl Pyrroles” |
M. Hügle, X. Lucas, D. Ostrovskyi, P. Regenass, S. Gerhardt, O. Einsle, M. Hau, M. Jung, B. Breit, S. Günther, D. Wohlwend, Angew. Chem. 2017, 129, 11466-11480 ; (link) Angew. Chem. Int. Ed. 2017, 56,11312–11325.
(link) |
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214. | “Alkynes as Electrophlic or Nucleophilic Allylmetal Precursors in Transition Metal Catalysis” |
A. M. Haydl, B. Breit, T. Liang, M. J. Krische, Angew. Chem. 2017, 129, 11466-11480 ; (link) Angew. Chem. Int. Ed. 2017, 56,11312–11325.
(link) |
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213. | “Rhodium-Catalyzed Regioselective Domino Azlactone-Alkyne Coupling/Aza-Cope Rearrangement: Facile Acess to 2-Allyl-3-oxazolin-5-ones and Trisubstituted Pyridines” |
J. Kuang, S. Parveen, B. Breit, Angew. Chem. 2017, 129, 8542-8545 ; (link) Angew. Chem. Int. Ed. 2017, 56,8422-8425.
(link) |
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212. | “Chemo-, Regio-, and Enantioselective Rhodium-Catalyzed Allylation of Pyridazinones with Terminal Allenes” |
S. Parveen, C. Li, A. Hassan, B. Breit, Org. Lett. 2017, 19, 2326-2329.; (link)
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211. | “Rhodium-catalyzed addition of sulfonyl hydrazides to allenes: regioselective synthesis of branched allylic sulfones” |
V. Khakyzadeh, Y.-H. Wang, B. Breit, Chem. Commun. 2017, 53, 4966-4968.; (link)
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210. | “Transition-Metal-Catalyzed Regiodivergent and Stereoselective Access to Branched and Linear Allylated 4-Pyridones” |
J. Schmidt, C. Li, B. Breit, Chem. Eur. J. 2017, 23, 6531-6534; (link)
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209. | “Regio- and Enantioselective Rhodium-Catalyzed Addition of 1,3-Diketones to Allenes: Construction of Asymmetric Tertiary and Quaternary All Carbon Centers” |
T. M. Beck, B. Breit, Angew. Chem. 2017, 129, 1929-1933 ; (link) Angew. Chem. Int. Ed. 2017, 56, 1903-1907. (link) |
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208. | “Enantioselective and Regiodivergent Addition of Purines to Terminal Allenes: Synthesis of Abacavir” |
N. Thieme, B. Breit, Angew. Chem. 2017, 129, 1542-1546 ; (link) Angew. Chem. Int. Ed. 2017, 56, 1520-1524. (link) |
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207. | “The Total Synthesis of Epothilone D as a Yardstick for Probing New Methodologies” |
A. Haydl, B. Breit , Chem. Eur. J. 2017, 23, 541-545; (link)
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2016 | |
206. | “Preparation data of the bromodomains BRD3(1), BRD3(2), BRD4(1), and BRPF1B and crystallization of BRD4(1)-inhibitor complexes” |
M. Hügle, X. Lucas, G. Weitzel, D. Ostrovskyi, B. Breit, S. Gerhardt, S. Schmidtkunz, M. Jung, R. Schüle, O. Einsle, S. Günther, D. Wohlwend, Data Brief. 2016, 93, 1370-1374; (link)
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205. | “Regioselective Rhodium-Catalyzed Addition of β-Keto Esters, β-Keto Amides and 1,3-Diketones to Internal Alkynes” |
T. M. Beck, B. Breit, Eur. J. Org. Chem. 2016, 93, 5839-5844; (link)
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204. | “Rhodium-Catalyzed Diastereoselective Cyclization of Allenylsufolnylcarbamates: A Stereodivergent Approach to 1,3-Aminoalcohol Derivatives” |
P. Spreider, A. Haydl, M. Heinrich, B. Breit Angew. Chem. 2016, 128, 15798-15802 ; (link) Angew. Chem. Int. Ed. 2015, 55, 15569-15573. (link) |
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203. | “Rhodium-Catalyzed Addition of Carboxylic Acids to Terminal Alkynes towards Z-Enol Esters ” |
S. Ganss, J. Pedroni, A. Lumbroso, G. Leonhardt-Lutterbeck, A. Meißner, S. Wei, H.-J. Drexler, D. Heller, B. Breit, Org. Synth. 2016, 93, 367-384; (link)
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202. | “Rhodium-Catalyzed Dynamic Kinetic Asymmetric Allylation of Phenols and 2-Hydroxypyridines” |
P.C. Li, B. Breit, Chem. Eur. J. 2016, 22, 14655-14663 ; (link)
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201. | “Tofacitinib and analogs as inhibitors of the histone kinase PRK1 (PKN1)” |
D. Ostrovskyi, T. Rumpf, J. Eib, A. Lumbroso, I. Slynko, S. Klaeger, S. Heinzlmeir, M. Forster, M. Gehringer, E. Pfaffenrot, S. M. Bauer, K. Schmidtkunz, S. Wenzler, E. Metzgr, B. Kuster, R. Schüle, W. Sippl, B. Breit, M. Jung, Future Med. Chem. 2016, 8, 1537-1551 ; (link)
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200. | “Branching Out: Rhodium-Catalyzed Allylation with Alkynes and Allenes” |
P. Koschker, B. Breit, Acc. Chem. Res. 2016, 49, 1524-1536 ; (link)
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199. | “Enantioselective Rhodium-Catalyzed Atom-Economical Macrolactonization” |
S. Ganss, B. Breit, Angew. Chem. 2016, 128, 9890-9894 ; (link) Angew. Chem. Int. Ed. 2015, 55, 9738-9742. (link) |
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198. | “Rhodium-Catalyzed Enantioselective Intermolecular Hydroalkoxylation of Allenes and Alkynes with Alcohols Leading to Branched Allylic Ethers” |
Z. Liu, B. Breit, Angew. Chem. 2016, 128, 8580–8583 ; (link) Angew. Chem. Int. Ed. 2016, 55, 8440-8443. (link) |
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197. | “Stereodivergent and Protecting-Group-Free Synthesis of the Helicascolide Family: A Rhodium-Catalyzed Atom-Economical Lactonization Strategy” |
A. Haydl, D. Berthold, P. A. Spreider, B. Breit, Angew. Chem. 2016, 128, 5859–5863 ; (link) Angew. Chem. Int. Ed. 2016, 55, 5765–5769. (link) |
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196. | “Regioconvergent and Enantioselective Rhodium-Catalyzed Hydroamination of Internal and Terminal Alkynes: A Highly Flexible Access to Chiral Pyrazoles” |
A. M. Haydl, L. J. Hilpert, B. Breit, Chem. Eur. J. 2016, 22, 6547-6551 ; (link)
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195. | “Rhodium-Catalyzed Chemo- and Regioselective Decarboxylative Addition of β-Ketoacids to Alkynes” |
C. Li, C. P. Grugel, B. Breit, Chem. Commun. 2016, 52, 5840-5843 ; (link)
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194. | “Asymmetric Synthesis of Allylic Amines via Hydroamination of Allenes with Benzophenone Imine” |
K. Xu, Y.-H. Wang, V. Khakyzadeh, Chem. Sci. 2016, 7, 3313-3316 (link)
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193. | “4-Acyl Pyrrole Derivatives Yield Novel Vectors for Designing Inhibitors of the Acetyl-Lysine Recognition Site of BRD4((1)” |
M. Hügle, X. Lucas, G. Weitzel, D. Ostrovskyi, B. Breit, S. Gerhard, O. Einsle, S. Günther, D. Wohlwend J. Med. Chem. 2016, 59, 1518–1530 ; (link)
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192. | “Regioselective Rhodium-Catalyzed Addition of 1,3-Dicarbonyl Compounds to Terminal Alkynes” |
T. M. Beck, B. Breit, Org. Lett. 2016, 18, 124–127 ; (link)
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2015 | |
191. | “Z-Selective Hydrothiolation of Racemic 1,3-Disubstituted Allenes: An Atom-Economic Rhodium-Catalyzed Dynamic Kinetic Resolution” |
A. B. Pritzius, B. Breit, Angew. Chem. 2015, 127, 16044–16048; (link) Angew. Chem. Int. Ed. 2015, 54, 15818–15822. (link) |
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190. | “Atom-Economical Dimerization Strategy by the Rhodium-Catalyzed Addition of Carboxylic Acids to Allenes: Protecting-Group-Free Synthesis of Clavosolide A and Late-Stage Modification” |
A. Haydl, B. Breit, Angew. Chem. 2015, 127, 15750–15754 ; (link) Angew. Chem. Int. Ed. 2015, 54, 15530–15534. (link) |
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189. | “Cuticular Hydrocarbon Pheromones for Social Behavior and Their Coding in the Ant Antenna” |
K. R. Sharma, B. L. Enzmann, Y. Schmidt, et al. B. Breit, J. Liebig, A. Ray, Cell Reports, 2015 (link) |
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188. | “Asymmetric synthesis of N-allylic indoles via regio- and enantioselective allylation of aryl hydrazines” |
K. Xu, T. Gilles, B. Breit, Nat. Commun., 2015 6, 7616; (link) |
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187. | “ Enantioselective formation of tertiary and quaternary allylic C–N bonds via allylation of tetrazoles ” |
K. Xu, W. Raimondi, T. Bury, B. Breit, Chem. Commun., 2015 51, 10861-00863; (link) |
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186. | “Regio- and Enantioselective Synthesis of N-Substituted Pyrazoles by Rhodium-Catalyzed Asymmetric Addition to Allenes” |
A. M. Haydl, K. Xu, B. Breit, Angew. Chem. 2015, 127, 7255-7259; (link) Angew. Chem. Int. Ed. 2015, 54, 7149-7153. (link) |
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185. | “Rhodium-Catalyzed Hydroformylation of 1,1-Disubstituted Allenes Employing the Self-Assembling 6-DPPon System” |
A. Köpfer, B. Breit, Angew. Chem. 2015, 127, 7017-7021; (link) Angew. Chem. Int. Ed. 2015, 54, 6913-6917. (link) |
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184. | “Paraformaldehyde and Methanol as C1 Feedstocks in Metal-Catalyzed C-C Couplings of π-Unsaturated Reactants: Beyond Hydroformylation” |
B. Sam, B. Breit, M. J. Krische, Angew. Chem. 2015, 127, 3317-3325; (link) Angew. Chem. Int. Ed. 2015, 54, 3267-3274. (link) |
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183. | “Asymmetric Rhodium-Catalyzed Addition of Thiols to Allenes: Synthesis of Branched Allylic Thioethers and Sulfones” |
A. B. Pritzius, B. Breit, Angew. Chem. 2015, 1273164-3168; (link) Angew. Chem. Int. Ed. 2015, 54, 3121-3125. (link) |
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182. | “Structural Characterization of O- and C-Glycosylating Variants of the Landomycin Glycosyltransferase LanGT2” |
H. K. Tam, J. Härle,
S. Gerhardt, J. Rohr, G. Wang, J. S. Thorson, A. Bigot, M. Lutterbeck, W. Seiche,B. Breit,
A Bechthold, O. Einsle, Angew. Chem. 2015, 127, 2853-2857; (link) Angew. Chem. Int. Ed. 2015, 54, 2811-2815. (link) |
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181. | “Enantioselective Redox-Neutral Rh-Catalyzed Coupling of Terminal Alkynes with Carboxylic Acids Toward Branched Allylic Esters” |
P. Koschker, M. Kähny, B. Breit, J. Am. Chem. Soc., 2015 137 (8), 3131-3137; (link) |
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180. | “Probing o-Diphenylphosphanyl Benzoate (o-DPPB)-Directed C–C Bond Formation: Total Synthesis of Dictyostatin” |
S. Wünsch, B. Breit, Chem. Eur. J. 2015, 21, 2358–2363; (link) |
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179. | “Easily Accessible TADDOL-Derived Bisphosphonite Ligands: Synthesis and Application in the Asymmetric Hydroformylation of Vinylarenes” |
S. Allmendinger, H. Kinuta, B. Breit, Adv. Synth. Catal. 2015, 357, 41-45; (link) |
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178. | “Full kinetic analysis of a rhodium-catalyzed hydroformylation: beyond the rate-limiting step picture” |
U. Gellrich, T. Koslowski, B. Breit, Cat. Sci. Technol., 2015 5 , 129-133; (link) |
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2014 | |
177. | “Direct Transformation of Terminal Alkynes to Branched Allylic Sulfones” |
K. Xu, V. Khakyzadeh, T. Bury, B. Breit, J. Am. Chem. Soc., 2014 136 , 16124-16127; (link) |
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176. | “Rhodium-Catalyzed Chemo-, Regio-, and Enantioselective Addition of 2-Pyridones to Terminal Allenes” |
C. Li, M. Kähny, B. Breit, Angew. Chem. 2014, 126, 14000-14004; (link) Angew. Chem. Int. Ed. 2014, 53, 13780-13784. (link) |
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175. | “New phosphorus self-assembling ligands for the tandem hydroformylation-Wittig olefination reaction of homoallylic alcohols – A key step for stereoselective pyran synthesis” |
Q. Ruan, L. Zhou, B. Breit, Cat. Commun. 2014, 53, 87*90; (link) |
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174. | “Unlocking the N2 Selectivity of Benzotriazoles: Regiodivergent and Highly Selective Coupling of Benzotriazoles with Allenes” |
K. Xu, N. Thieme, B. Breit, Angew. Chem. 2014, 126, 7396-7399; (link) Angew. Chem. Int. Ed. 2014, 53, 7268-7271; (link) |
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173. | “Efficient Synthesis of New Fluorinated Building Blocks by means of Hydroformylation” |
L. Fanfoni, L. Diab, T. Smejkal, B. Breit, Chimia 2014, 19, 68, 371-377; (link) |
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172. | “Mechanistic insight into the ruthenium-catalysed anti-Markovnikov hydration of alkynes using a self-assembled complex: a crucial role for ligand-assisted proton shuttle processes” |
B. Breit, U. Gellrich, T. Li, J. M. Lynam, L. M. Miller, N. E. Pridmore, J. M. Slattery, A. C. Whitwood, Dalton Trans. 2014, 43, 11277-11285.; (link) |
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171. | “Tandem Regioselective Rhodium-Catalyzed Hydroformylation-Enantioselective Aminocatalytic anti-Mannich Reaction” |
S. Diezel, B. Breit, Synthesis. 2014, 46, 1311-1320; (link) |
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170. | “Hydroformylation and Related Carbonylation Reactions of Alkenes, Alkynes, and Allenes” |
B. Breit and L. Diab, In: Gary A. Molander and Paul Knochel (eds.), Comprehensive Organic Synthesis, 2nd Edition, Vol 4, Oxford: Elsevier 2014, pp. 995-1053; (link) |
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169. | “Atom-Economic, Regiodivergent, and Stereoselective Coupling of Imidazole Derivatives with Terminal Allenes” |
K. Xu, N. Thieme, B. Breit, Angew. Chem. 2014, 126, 2194-2197; (link) Angew. Chem. Int. Ed. 2014, 53, 2162-2165. (link) |
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168. | “Total Synthesis of (18S)- and (18R)-Homolargazole by Rhodium-Catalyzed Hydrocarboxylation” |
C. Schotes, D. Ostrovskyi, J. Senger, K. Schmidtkunz, M. Jung, B. Breit, Chem. Eur. J. 2014, 20, 2164-2168; (link) |
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167. | “Mechanistic Investigations of the Rhodium Catalyzed Propargylic CH Activation” |
U. Gellrich, A. Meißner, A. Steffani, M. Kähny, H.-J. Drexler, D. Heller, D. A. Plattner, B. Breit, J. Am. Chem. Soc. 2014, 136, 1097-1104; (link) |
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166. | “Rhodium-Catalyzed Chemo- and Regioselective Decarboxylative Addition of β-Ketoacids to Allenes: Efficient Construction of Tertiary and Quaternary Carbon Centers” |
C. Li, B. Breit, J. Am. Chem. Soc., 2014, 136 (3), 862–865; (link) |
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2013 | |
165. | “Realistic Energy Surfaces for Real World Systems: an IMOMO CCSD(T):DFT scheme for the Rhodium Catalyzed Hydroformylation with the 6-DPPon ligand” |
U. Gellrich, D. Himmel, M. Meuwly, B. Breit, Chem. Eur. J. 2013, 19, 16272-16281; (link) |
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164. | “Tandem decarboxylative hydroformylation-hydrogenation reaction of α,β-unsaturated carboxylic acids toward aliphatic alcohols under mild conditions employing a supramolecular catalyst system” |
L. Diab, U. Gellrich, B. Breit, Chem. Commun. 2013, 49,9737-9739; (link) |
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163. | “Tandem Hydroformylation/Biginelli Reaction” |
D. Fuchs, M. Nasr-Esfahani, L. Diab, T. Smejkal, B. Breit, Synlett 2013, 13, 1657-1662; (link) |
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162. | “Room Temperatur Ambient Pressure (RTAP)-Hydroformylation in Water Using a Self-Assembling Ligand” |
A. T. Straub, M. Otto, I. Usui, B. Breit, Adv. Synth. Cat. 2013, 75, 2071-2075; (link) |
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161. | “A Systematic Investigation of Coinage Metal Carbonyl Complexes Stabilized by Fluorinated Alkoxy Aluminates” |
J. Schaefer, A. Kraft, S. Reininger, G. Santiso-Quinones, D. Himmel, N. Trapp, U. Gellrich, B. Breit, I. Krossing Chem. Eur. J. 2013, 19, 12468-12485; (link) |
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160. | “Development of an Improved Rhodium-Catalyst for Z-selective anti-Markovnikov Addition of Carboxylic Acids to Terminal Alkynes” |
S. Wei, J. Pedroni, A. Meißner, A. Lumbroso, H.-J. Drexler, D. Heller, B. Breit, Chem. Eur. J. 2013, 19, 12067-12076; (link) |
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159. | “Bernhard Breit – Author Profile” |
B. Breit, Angew. Chem. 2013, 125, 10072-10073; (link) Angew. Chem. Int. Ed. 2013, 52, 9888-9889; (link) |
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158. | “Rhodium-catalyzed hydroformylation of alkynes employing a self-assembling ligand system” |
V. Agabekov, W. Seiche, B. Breit, Chem. Sci. 2013, 4, 2418-2422; (link) |
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157. | “Regiodivergent reductive coupling of 2-substituted dienes to formaldehyde employing ruthenium or nickel catalyst: hydrohydroxymethylation via transfer hydrogenation” |
A. Köpfer, B. Sam, B. Breit, M. Krische, Chem. Sci. 2013, 4, 1876-1880; (link) |
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156. | “Catalytic Hydrogenation of Amides to Amines under Mild Conditions” |
M. Stein, B. Breit, Angew. Chem. 2013, 125, 2287-2290; (link) Angew. Chem. Int. Ed. 2013, 52, 2231-2234; (link) |
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155. | “Nachruf Horst Prinzbach (1931-2012)” |
B. Breit, R. Brückner, Nachr. Chem. 2013, 61, 163; |
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154. | “Catalytic Asymmetric Synthesis of Allylic Alcohols and Derivatives and their Applications in Organic Synthesis” |
A. Lumbroso, M. L. Cooke, B. Breit, Angew. Chem. 2013, 125, 1942-1986(link); Angew. Chem. Int. Ed. 2013, 52, 1890-1932; (link) |
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153. | “Potent Inhibitors of Malarial Aspartic Proteases, the Plasmepsins, by Hydroformylation of Substituted 7-Azanorbornenes” |
V. Aureggi, V. Ehmke, J. Wieland, W. B. Schweizer, B. Bernet, D. Bur, S. Meyer, M. Rottmann, C. Freymond, R. Brun, B. Breit, F. Diederich, Chem. Eur. J. 2013, 19, 155-164; (link) |
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2012 | |
152. | “Hydrogen-Bond and Solvent Dynamics in Transition Metal Complexes: A Combined Simulation and NMR-Investigation” |
J. Huang, D. Häussinger, U. Gellrich, W. Seiche, B. Breit, M. Meuwly, J. Phys. Chem. B 2012, 116, 14406-14415 ; (link) |
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151. | “Dicarbonyl(acetylacetonato) Rhodium(I)” |
B. Breit, Encyclopedia of Reagents for Organic Synthesis, Eds. D. Crich, A Charette, P. L. Fuchs, T. Rovis, first update 2012, John Wiley & Sons Ltd. |
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150. | "Enantioselective Rhodium-Catalyzed Synthesis of Branched Allylic Amines by Intermolecular Hydroamination of Terminal Allenes" |
M. L. Cooke, Kun Xu, B. Breit, Angew. Chem. 2012, 124, 11034-11037; (link) Angew. Chem. Int. Ed. 2012, 51, 10876-10879. (link) |
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149. | "Mechanistic Insights into a Supramolecular Self-Assembling Catalyst System: Evidence for Hydrogen-Bonding during Rhodium-Catalyzed Hydroformylation" |
U. Gellrich, W. Seiche, M. Keller, B. Breit, Angew. Chem. 2012, 124, 11195-11200; (link) Angew. Chem. Int. Ed. 2012, 51, 11033-11038. (link) |
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148. |
"Assignment of Relative Configuration of Desoxypropionates by 1H NMR Spectroscopy: Method Development, Proof of Principle by Asymmetric Total Synthesis of Xylarinic Acid A and Applications" |
Y. Schmidt, K. Lehr, L. Colas, B. Breit, Chem. Eur. J. 2012, 18, 7071-7081.(link) | |
147. |
"Preparation of Alkylmagnesium Reagents from Alkenes through Hydroboration and Boron-Magnesium Exchange" |
M. Reichle, B. Breit, Angew. Chem. 2012, 124, 5828-5832; (link) Angew. Chem. Int. Ed. 2012, 51, 5730-5734. (link) highlighted in SynFacts as Synfact of the Month September (link) |
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146. |
"Tandem Rhodium-Catalyzed Hydroformylation-Hydrogenation of Alkenes by Employing a Cooperative Ligand System" |
D. Fuchs, G. Rousseau, L. Diab, U. Gellrich, B. Breit, Angew. Chem. 2012, 124, 2220-2224; (link) Angew. Chem. Int. Ed. 2012, 51, 2178-2182. (link) |
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145. |
"Atom Economic Macrolactonization and Lactonization via Redox-Neutral Rhodium-Catalyzed Coupling of Terminal Alkynes with Carboxylic Acids" |
A. Lumbroso, N. Abermil, B. Breit, Chem. Sci. 2012, 3, 789-793. (link) |
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2011 | |
144. |
"Enantioselective Synthesis of Branched Allylic Esters via Rhodium-Catalyzed Coupling of Allenes with Carboxylic Acids" |
P. Koschker, A. Lumbroso, B. Breit, J. Am. Chem. Soc. 2011, 133, 20746-20749. (link) |
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143. |
"Rhodium(I)-Catalyzed 1,4-Addition of Arylboronic Acids to Acrylic Acids in Water: One-Step Preparation of 3-Arylpropionic Acids" |
N. R. Vautravers, B. Breit, Synlett 2011, 2517-2520. (link) |
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142. |
"Stereoselective and Diversity-Oriented Synthesis of Trisubstituted Allylic Alcohols and Amines" |
Y. Schmidt, B. Breit, Chem. Eur. J. 2011, 17, 11789-11796. (link) |
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141. |
"Stereoselective Synthesis of Trisubstituted Olefins by a Directed Allylic Substitution Strategy" |
Y. Schmidt, B. Breit, Chem. Eur. J. 2011, 17, 11780-11788. (link) |
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140. |
"Phosphorylation of Tip60 by GSK-3 Determines the Induction of PUMA and Apoptosis by p53" |
C. Charvet, M. Wissler, P. Brauns-Schubert, S.J. Wang, Y. Tang, F. C. Sigloch, H. Mellert, M Brandenburg, S. E. Lindner, B. Breit, D. R. Green, S. B. McMahon, C. Borner, W. Gu, U. Maurer, Molecular Cell 2011, 42, 584-596. (link) |
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139. |
"Formation of Quaternary Carbon Centers by Highly Regioselective Hydroformylation with Catalytic Amounts of a Reversibly Bound Directing Group" |
Y. Ueki, H. Ito, I. Usui, B. Breit, Chem Eur. J. 2011, 17, 8555-8558. (link) |
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138. |
"Divergent Regioselectivity in the Synthesis of Trisubstituted Allylic Alcohols by Nickel- and Ruthenium-Catalyzed Alkyne Hydroxymethylation with Formaldehyde" |
C. C. Bausch, R. L. Patman, B. Breit, M. J. Krische, Angew. Chem. 2011, 123, 5805-5808; (link) Angew. Chem. Int. Ed. 2011, 50, 5687-5690. (link) | |
137. |
"Inter- and Intramolecular Hydroacylation of Alkenes Employing a Bifunctional Catalyst System" |
N. R. Vautravers, D. D. Regent, B. Breit, Chem. Commun. 2011, 6635-6637. (link) | |
136. |
"Removable Directing Groups in Organic Synthesis and Homogeneous Catalysis" |
G. Rousseau, B. Breit, Angew. Chem. 2011, 123, 2498-2543; (link) Angew. Chem. Int. Ed. 2011, 50, 2450-2494. (link) | |
135. |
"Redox-Neutral Atom Economic Rhodium-Catalyzed Coupling of Terminal Alkynes with Carboxylic Acids Toward Branched Allylic Esters" |
A. Lumbroso, P. Koschker, N. R. Vautravers, B. Breit, J. Am. Chem. Soc. 2011, 133, 2386-2389. (link) | |
134. |
"Iron Nanoparticles Supported on Chemically-Derived Graphene: Catalytic Hydrogenation with Magnetic Catalyst Separation" |
M. Stein, J. Wieland, P. Steurer, F. Tölle, R. Mülhaupt, B. Breit, Adv. Synth. Cat. 2011, 353, 523-527. (link) | |
133. |
"Diastereoselective Hydroformylation of 2,5-Cyclohexadienyl-1-carbinols with Catalytic Amounts of a Reversibly Bound Directing Group" |
I. Usui, K. Nomura, B. Breit, Org. Lett. 2011, 13, 612-615. (link) | |
132. |
"Ligand Self-Assembling through Complementary Hydrogen Boning in the coordination Sphere of a Transition Metal Center: The Phosphanylpyridin-2(1H)-one System" |
U. Gellrich, J. Huang, W. Seiche, M. Keller, M. Meuwly, B. Breit, J. Am. Chem. Soc. 2011, 133, 964-975. (link) | |